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Dr. Guofu Zi
(自国甫博士) Principal Investigator Organic and Organometallic Chemistry Address Room 415B
(Office), 417 (Lab) Chemistry
Hall 北京师范大学化学学院 北京100875,中国 Phone: 18911558150 Fax: 86-10-5880 2075 E-mail: gzi@bnu.edu.cn |
Biography Born 1972; |
Research
Interests
Organic Synthesis, Asymmetric Synthesis, Organometallic Synthesis and Homogenous Catalysis.
Work in Dr. Zi's research group is
directed toward the synthesis and study of new and unusual molecular
organometallic compounds of the p-, d- and f-block elements. The emphasis is on
preparing compounds that exhibit novel reactivity, selectivity (including stereoselectivity and enantioselectivity)
and/or catalytic behavior (homogeneously), with the discovery of new
applications (new chemical reactions) of these compounds to catalysis and
organic synthesis. In addition to the dry-box and Schlenk
techniques used to prepare and manipulate compounds, we exploit a variety of
characterization methods, including NMR, IR, elemental analysis and X-ray
crystallography.
Positions
Open
The mission of Dr. Zi’s group includes the education and training of the next generation of scientists and teachers to promote national science and education goals. Every year, one or two positions are available for M.Sc, Ph. D students and Postdoctoral Fellows:
Graduate students:
Prospective graduate students from chemistry department are very welcome to
visit our lab and contact Dr. Zi for more information
about ongoing research projects.
Postdoctoral applicants: Send cover
letter, CV, and three letters of recommendation to Dr. Zi.
Undergraduates: Interested sophomores or juniors should email Dr. Zi with a cover letter, CV, and three references.
Current Members
DSc Students: Yi Heng (衡义, 1st year)
MSc Students:
Past Members
Li Xiang (向丽, MSc, 2009); Li'na Gu (古丽娜, MSc, 2009, Exchange Student from Nankai
University); Qiuwen Wang (王秋文, DSc, 2010); Xue Liu (刘雪, MSc, 2010); Furen Zhang (张富仁, DSc, 2011); Haiyan Zhang (张海燕, MSc, 2011); Yuqiao Liu (刘玉巧, MSc, 2011, Exchange
Student from Nankai University); Dongna
Fan (范冬娜, MSc, 2012, Exchange Student from Nankai University); Wenshan Ren (任文山, DSc, 2012); Liang Chen (陈亮, MSc, 2013); Ning
Zhao (赵宁, DSc,
2014); Enwei Zhou (周恩伟, MSc, 2016); Bo Fang (方波, DSc, 2016); Pikun Yang (杨丕堃, MSc, 2017); Lei
Zhang (张磊, DSc,
2017); Congcong
Zhang (张丛丛, DSc, 2019)
Representative Publications (Since 2001; Impact Factor > 2.0)
124. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi,* Wanjian Ding,* Laurent Maron, and Marc D. Walter*. Experimental and Computational Studies on Uranium Diazomethanediide Complexes. Angew. Chem. Int. Ed. 2023, 62, e202313010.
123. Xiaoxue Wu, Yanhao Su, Guofu Zi, Weiping Ye*, and Guohua Hou*. “Rh-Catalyzed Asymmetric Hydrogenation of α‑Substituted Alkenyl Sulfones: Highly Chemo- and Enantioselective Access to Chiral Sulfones”. Org. Lett. 2023, 25, 6858-6862.
122. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Reactivity of a Lewis base supported uranium terminal imido metallocene towards small molecules”. Dalton Trans. 2023, 52, 13618-13630.
121. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “A Comprehensive Study Concerning the Synthesis, Structure and Reactivity of Terminal Uranium Oxido, Sulfido and Selenido Metallocenes”. J. Am. Chem. Soc. 2023, 145, 14839-14855.
120. Chaochao Xie, Guiying Xiao, Qianling Guo, Xiaoxue Wu, Guofu Zi, Wanjian Ding*, and Guohua Hou*. “Highly enantioselective Rh-catalyzed asymmetric reductive dearomatization of multi-nitrogen polycyclic pyrazolo[1,5-a]pyrimidines”. Chem. Sci. 2023, 14, 9048-9054.
119. Siwei Wang, Chaochao Xie, Yu Zhu, Guofu Zi, Zhanbin Zhang*, and Guohua Hou*. “Enantioselective Synthesis of Chiral Cyclic Hydrazines by Ni-Catalyzed Asymmetric Hydrogenation”. Org. Lett. 2023, 25, 3644-3648.
118. Chaochao Xie, Qianling Guo, Zhihong Yang, Guofu Zi, Yuping Huang*,and Guohua Hou*. “Enantioselective synthesis of chiral 2,2,2-trifluoroethyl lactams via asymmetric Hydrogenation”. Org. Chem. Front. 2023, 10, 2498-2504.
117. Suna Han, Xin Shen, Xiaoxue Wu, Chaochao Xie, Guofu Zi, and Guohua Hou*. “Highly diastereo- and enantioselective copper-catalyzed methylboration of 1,2-dihydroquinolines and 2H-chromenes”, Org. Chem. Front. 2023, 10, 806-812.
116. Tongyu Li, Dongwei Wang, Yi Heng, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Influence of the 1,2,4-Tri-tert-butylcyclopentadienyl Ligand on the Reactivity of the Uranium Bipyridyl Metallocene [h5-1,2,4-(Me3C)3C5H2]2U(bipy)”. Organometallics 2023, 42, 392-406.
115. Yi Heng, Tongyu Li, Dongwei Wang, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Synthesis and Reactivity of the Uranium Bipyridyl Metallocene [h5-1,3-(Me3C)2C5H3]2U(bipy)”, Organometallics 2023, 42, 91-113.
114. Guiying Xiao, Chaochao Xie, Qianling Guo, Guofu Zi, Guohua Hou,* and Yuping Huang*. “Highly enantioselective Ni-catalyzed asymmetric hydrogenation of β,β-disubstituted acrylic acids”, Org. Chem. Front. 2022, 9, 4472-4477.
113. Shichun Wang, Yi Heng, Tongyu Li, Dongwei Wang, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Intrinsic reactivity of [h5-1,3-(Me3Si)2C5H3]2U(h4-C4Ph2) in small molecule activation”, Dalton Trans. 2022, 51, 11072-11085.
112. Shichun Wang, Dongwei Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Synthesis, Structure and Reactivity of the Uranium Bipyridyl Complex [{h5-1,2,4-(Me3Si)3C5H2}2U(bipy)]”, Organometallics 2022, 41, 1543-1557.
111. Guiying Xiao, Chaochao Xie, Qianling Guo, Guofu Zi, Guohua Hou,* and Yuping Huang*. “Nickel-catalyzed Asymmetric Hydrogenation of γ-Keto Acids, Esters and Amides to Chiral γ-Lactones and γ-Hydroxy Acid Derivatives”, Org. Lett. 2022, 24, 2722-2727
110. Shichun Wang, Tongyu Li, Yi Heng, Dongwei Wang, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Small Molecule Activation Mediated by [h5-1,3-(Me3Si)2C5H3]2U(bipy)”, Inorg. Chem. 2022, 61, 6234-6251.
109. Shichun Wang, Yi Heng, Tongyu Li, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Synthesis and reactivity of the uranium phosphinidene metallocene [h5-1,3-(Me3Si)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPMe3): Influence of the coordinated Lewis base”, Dalton Trans. 2021, 50, 12502-12516.
108. Chaoqiong Wang, Fang Xie, Qianling Guo, Chaochao Xie, Guofu Zi, Weiping Ye, Zhangtao Zhou, Guohua Hou*, and Zhanbin Zhang*. “Enantioselective Synthesis of Chiral Phosphonates via Rh/fspiroPhos Catalyzed Asymmetric Hydrogenation of β,β-Disubstituted Unsaturated Phosphonates”, J. Org. Chem. 2021, 86, 12034-12045.
107. Guiying Xiao, Shuang Xu, Chaochao Xie, Guofu Zi, Weiping Ye, Zhangtao Zhou, Guohua Hou*, and Zhanbin Zhang*. “Enantioselective Synthesis of Chiral Substituted 2,4-Diketoimidazolidines and 2,5-Diketopiperazines via Asymmetric Hydrogenation”, Org. Lett. 2021, 23, 5734-5738.
106. Shichun Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the reactivity of the Uranium Phosphinidene [h5-1,3-(Me3Si)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPPh3)”, Organometallics 2021, 40, 2149-2165.
105. Deqiang Wang, Shichun Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Reactivity Studies Involving a Lewis Base Supported Terminal Uranium Phosphinidene Metallocene [h5-1,3-(Me3C)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPMe3)”, Dalton Trans. 2021, 50, 8349-8363.
104. Deqiang Wang, Wanjian Ding, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Uranium versus Thorium: Synthesis and Reactivity of [h5-1,2,4-(Me3C)3C5H2]2U[h2-C2Ph2]”, Chem. Eur. J. 2021, 27, 6767-6782.
103. Deqiang Wang, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (h5-C5Me5)2U(=P-2,4,6-iPr3C6H2)(OPPh3)”, Organometallics 2021, 40, 383-396.
102. Deqiang Wang, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “(h5-C5Me5)2U(=P-2,4,6-tBu3C6H2)(OPMe3) Revisited – Its Intrinsic Reactivity towards Small Organic Molecules”, Organometallics 2020, 39, 4085-4101.
101. Deqiang Wang, Shichun Wang, Guohua Hou, Guofu Zi*, Marc D. Walter*. “A Lewis Base Supported Terminal Uranium Phosphinidene Metallocene”, Inorg. Chem. 2020, 59, 14549-14563.
100. Deqiang Wang, Wanjian Ding, Guohua Hou, Guofu Zi*, Marc D. Walter*. “Experimental and Computational Studies on a Base-Free Terminal Uranium Phosphinidene Metallocene”, Chem. Eur. J. 2020, 26, 16888-16899.
99. Qiaozhi Yan, Xin Shen, Guofu Zi, and Guohua Hou*. “Rh-Catalyzed Asymmetric Hydrogenation of α,β- and β,β-Disubstituted Unsaturated Boronate Esters”, Chem. Eur. J. 2020, 26, 5961-5964.
98. Xiufen Li, Chaoqiong Wang, Jianqiao Song; Zhihong Yang, Guofu Zi, and Guohua Hou*. “Copper-Catalyzed Asymmetric Hydroboration of 2H-Chromenes Using a Chiral Diphosphine Ligand”, J. Org. Chem. 2019, 84, 8638-8645.
97. Yongsong Wang, Congcong Zhang, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “Preparation of a potassium chloride bridged thorium phosphinidiide complex and its reactivity towards small organic molecules”, New J. Chem. 2019, 43, 9527-9539.
96. Congcong Zhang, Yongsong Wang, Guohua Hou, Wanjian Ding, Guofu Zi*, and Marc D. Walter*. “Experimental and computational studies on a three-membered diphosphido thorium metallaheterocycle [h5-1,3-(Me3C)2C5H3]2Th[h2-P2(2,4,6-iPr3C6H2)2]”, Dalton Trans. 2019, 48, 6921-6930.
95. Suna Han, Xin Shen, Duanyang Kong, Guofu Zi, Guohua Hou,* and Jiaxin Zhang*. “Cu-Catalyzed Asymmetric Hydroboration of Naphthylallylic Compounds for Enantioselective Synthesis of Chiral Boronates”, J. Org. Chem. 2019, 84, 4318-4329.
94. Congcong Zhang, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “An Alkali-Metal Halide-Bridged Actinide Phosphinidiide Complex”, Inorg. Chem. 2019, 58, 1571-1590.
93. Qiaozhi Yan, Guiying Xiao, Ying
Wang, Guofu Zi, Zhanbin Zhang, and Guohua Hou*. “Highly Efficient Enantioselective
Synthesis of Chiral Sulfones by Rh-Catalyzed
Asymmetric Hydrogenation”, J. Am. Chem. Soc. 2019, 141, 1749-1756.
92. Congcong Zhang, Guohua Hou,
Guofu Zi*,
and Marc D. Walter. “A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic
molecules”, Dalton Trans. 2019,
48, 2377-2387.
91. Congcong Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “A Base-Free Terminal Actinide Phosphinidene Metallocene:
Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2018, 140, 14511-14525.
90. Guofu Zi*. “Recent developments in actinide metallacycles”,
Chem. Commun.
2018, 54, 7412-7430.
89. Duanyang Kong, Suna Han, Guofu Zi, Guohua Hou,* and Jiaxin Zhang*. “Enantioselective Synthesis of Boryl
Tetrahydroquinolines via Cu-Catalyzed Hydroboration”,
J. Org. Chem. 2018, 83, 1924-1932.
88. Congcong Zhang, Pikun Yang, Enwei
Zhou, Xuebin Deng, Guofu Zi,* and Marc D. Walter*. “Reactivity
of a Lewis Base Supported Thorium Terminal Imido Metallocene towards Small Organic Molecules”, Organometallics 2017, 36, 4525-4538.
87. Lei Zhang, Congcong
Zhang, Guohua Hou, Guofu Zi,* and Marc
D. Walter*. “Small
Molecule Activation Mediated by a Uranium Bipyridyl Metallocene”, Organometallics 2017, 36,
1179-1187.
86. Lei Zhang, Guohua
Hou, Guofu Zi,* Wanjian Ding,* and
Marc D. Walter*. “Preparation of a uranium metallacyclocumulene
and its reactivity towards unsaturated organic molecules”, Dalton
Trans. 2017, 46,
3716-3728.
85. Lei Zhang, Bo Fang, Guohua Hou, Guofu Zi,* Wanjian Ding* and Marc D. Walter*. “Experimental and Computational
Studies on a Uranium Metallacyclocumulene”, Organometallics
2017, 36, 898-910.
84. Ying Zhang,
Qiaozhi Yan, Guofu Zi, Guohua Hou*. “Enantioselective Direct Synthesis of
Free Cyclic Amines via Intramolecular Reductive Amination”, Org. Lett. 2017, 19, 4215-4218.
83. Duanyang Kong, Suna Han, Rui
Wang, Meina Li, Guofu Zi, and Guohua
Hou*. “Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric
Cu-catalyzed borylation”, Chem. Sci. 2017, 8, 4558-4564.
82. Meina Li, Duanyang
Kong, Guofu Zi
and Guohua Hou*.
“Rh-Catalyzed Asymmetric Hydrogenation of 1,2-Dicyanoalkenes”,
J. Org. Chem. 2017, 82, 680-687.
81. Lei Zhang, Guohua Hou, Guofu
Zi,* Wanjian Ding,*
and Marc D. Walter*. “Influence of the 5f Orbitals on the Bonding and
Reactivity in Organoactinides: Experimental and
Computational Studies on a Uranium Metallacyclopropene”,
J. Am. Chem. Soc. 2016, 138, 5130-5142.
80. Pikun Yang, Enwei Zhou, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “Experimental
and Computational Studies on the Formation of Thorium-Copper Heterobimetallics”, Chem.-Eur.
J. 2016, 22, 13845-13849.
79. Pikun Yang, Enwei Zhou, Bo Fang, Guohua Hou, Guofu Zi*, and Marc
D. Walter*.
“Preparation of (h5-C5Me5)2Th(bipy) and Its Reactivity
toward Small Molecules” Organometallics
2016, 35, 2129-2139.
78. Lei Zhang, Bo Fang, Guohua
Hou, Lin Ai, Wanjian Ding*,
Marc D. Walter*, and Guofu Zi*. “Intrinsic reactivity of a uranium metallacyclopropene
toward unsaturated organic molecules”, Dalton
Trans. 2016, 45, 16441-16452.
77. Duanyang Kong, Meina Li, Guofu Zi, Guohua
Hou*, and Yong He*. “Enantioselective
Hydrogenation of Diarylmethanimines for Synthesis of
Chiral Diarylmethylamines”, J. Org. Chem. 2016, 81, 6640-6648.
76. Duanyang Kong, Meina Li, Rui Wang, Guofu Zi and Guohua
Hou.* “Asymmetric Hydrogenation of β-Aryloxy/Alkoxy Cinnamic Nitriles and
Esters”, Org. Lett.
2016, 18, 4916-4919.
75.
Duanyang Kong, Meina Li, Guofu
Zi and Gouhua Hou*. “Synthesis of Chiral Lactams via Asymmetric Hydrogenation
of α,β-Unsaturated Nitriles”, Org. Biomol. Chem. 2016,
14, 4046-4053.
74. Qiaozhi Yan, Duanyang
Kong, Wei Zhao, Guofu Zi, Guohua Hou*. “Enantioselective Hydrogenation of β,β-Disubstituted Unsaturated
Carboxylic Acids under Base-Free Conditions”, J. Org. Chem. 2016, 81,
2070-2077.
73. Duanyang Kong, Meina Li, Rui Wang, Guofu
Zi, Guohua Hou*. “Highly Efficient Asymmetric
Hydrogenation of Cyano-substituted Acrylate Esters
for Synthesis of Chiral γ-Lactams and
Amino Acids”, Org. Biomol. Chem. 2016, 14, 1216-1220.
72. Bo Fang, Guohua Hou, Guofu Zi*,
Wanjian Ding*, and Marc D. Walter*. “Steric and Electronic Influences of Internal Alkynes on the Formation
of Thorium Metallacycles: A Combined Experimental and
Computational Study”, Organometallics
2016, 35, 1384-1391.
71. Bo Fang, Lei Zhang, Guohua Hou, Guofu Zi,* De-Cai Fang* and
Marc D. Walter*. “C-H bond activation induced by thorium metallacyclopropene complexes: A combined experimental and
computational study”, Chem. Sci. 2015,
6, 4897-4906.
70. Bo Fang, Lei Zhang, Guohua Hou, Guofu
Zi,* De-Cai Fang*
and Marc D. Walter*. “Experimental and Computational Studies
on an Actinide Metallacyclocumulene Complex”, Organometallics 2015, 34, 5669-5681.
69. Enwei Zhou,
Wenshan Ren, Guohua Hou, Guofu
Zi,* De-Cai Fang*
and Marc D. Walter*. “Small Molecule Activation Mediated By a
Thorium Terminal Imido Metallocene”,
Organometallics 2015, 34, 3637-3647.
68. Ann Christin
Fecker, Matthias Freytag, Peter G. Jones, Ning Zhao, Guofu
Zi* and Marc D. Walter*. “Preparation of enantiomerically
pure open calcocene and strontocene
complexes and their application in ring opening polymerizations of rac-lactide”, Dalton Trans. 2015, 44, 16325-16331.
67. Qiaozhi
Yan, Duanyang Kong, Meina,
Li, Guohua Hou,* and Guofu Zi. “Highly Efficient Rh-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Nitriles”, J.
Am. Chem. Soc. 2015, 137,
10177-10181.
66. Man Liu, Duanyang Kong, Meina
Li, Guofu Zi
and Guohua Hou*.
“Iridium-Catalyzed Enantioselective Hydrogenation of β,β-Disubstituted Nitroalkenes”, Adv.
Synth. Catal. 2015, 357,
3875-3879.
65. Dao Zhang,* and Guofu Zi*. “N-Heterocyclic carbene
(NHC) complexes of group 4 transition metals”, Chem.
Soc. Rev. 2015, 44, 1898-1921.
64. Bo Fang, Guohua Hou,
Guofu Zi,*
De-Cai Fang* and Marc D. Walter*. “A thorium metallacyclopentadiene
complex: a combined experimental and computational study”, Dalton Trans. 2015, 44, 7927-7934.
63. Bo Fang, Wenshan Ren, Guohua Hou, Guofu
Zi,* De-Cai Fang,*
Laurent Maron,* and Marc D. Walter* “An Actinide Metallacyclopropene Complex: Synthesis, Structure,
Reactivity and Computational Studies”, J.
Am. Chem. Soc. 2014, 136,
17249-17261.
62. Wenshan Ren, Enwei Zhou, Bo
Fang, Guohua Hou, Guofu Zi*,
De-Cai Fang*, and Marc D. Walter*.
“Experimental and Computational Studies on the Reactivity of a Terminal Thorium
Imido Metallocene towards
Organic Azides and Diazoalkanes”,
Angew. Chem. Int. Ed. 2014, 53, 11310-11314.
61. Qiaozhi Yan, Man Liu, Duanyang
Kong, Guofu Zi,
and Guohua Hou*. “Highly Efficient Iridium-Catalyzed Asymmetric Hydrogenation of β-Acylamino Nitroolefins”, Chem. Commun. 2014, 50, 12870-12872.
60. Wenshan Ren, Enwei Zhou, Bo
Fang, Guofu Zi*,
De-Cai Fang*, and Marc D. Walter*. “Si-H
Addition followed by C-H bond activation induced by a terminal thorium imido metallocene: A combined
experimental and computational study”, Chem.
Sci. 2014, 5, 3165-3172.
59. Ning Zhao, Guohua Hou, Xuebin Deng, Guofu Zi*,
and Marc D. Walter*. “Group 4 metal complexes with new chiral pincer NHC-ligands:
Synthesis, structure and catalytic activity”, Dalton Trans. 2014, 43, 8261-8272.
58. Ning Zhao, Qiuwen
Wang, Guohua Hou, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of aluminum chloride complexes with chiral biaryl
Schiff-base ligands”, Inorg. Chem. Commun.
2014, 44, 86-90.
57. Wenshan Ren, Liang
Chen, Ning Zhao, Qiuwen
Wang, Guohua Hou, and Guofu Zi*.
“Synthesis, structure, and catalytic activity of organolanthanide
complexes with chiral biaryl Schiff-base ligands”, J. Organomet.
Chem. 2014, 758, 65-72.
56. Ning Zhao, Qiuwen
Wang, Guohua Hou, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of organoaluminum complexes with chiral biaryl Schiff-base ligands”, Inorg. Chim. Acta 2014,
413, 128-135.
55. Ning Zhao, Qiuwen
Wang, Guohua Hou, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of binuclear aluminum complexes with chiral biaryl-based
N2O ligands”, J. Organomet. Chem. 2014, 754, 51-58.
54. Ning Zhao, Qiuwen
Wang, Guohua Hou, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of binuclear aluminum choride complexes with
chiral biaryl-based ligands”, Inorg. Chem. Commun. 2014, 41, 6-10.
53. Wenshan Ren, Wayne W. Lukens, Guofu Zi*, Laurent Maron*,
and Marc D. Walter*. “Is the bipyridyl thorium metallocene a low-valent thorium
complex? A combined experimental and computational study”, Chem. Sci. 2013, 4, 1168-1174.
52. Liang Chen, Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, Guofu Zi*.
“Synthesis, structure, and catalytic
activity of titanium complexes with chiral biaryl
Schiff-base ligands”, Inorg. Chim. Acta 2013, 402, 140-155.
51. Wenshan Ren, Ning Zhao, Liang Chen, and Guofu
Zi*. “Synthesis, structure, and catalytic activity of benzyl thorium metallocenes”, Inorg. Chem. Commun. 2013, 30, 26-28.
50. Liang Chen, Yuqiao Liu, Guohua Hou, Haibin Song, Guofu Zi*.
“Synthesis, structure, and catalytic activity of a new chiral NHC-iridium(III)
complex”, Inorg. Chem. Commun.
2013, 29, 141-144.
49. Haibin Song*, Dongna
Fan, Yuqiao Liu, Guohua Hou, Guofu Zi*. “Synthesis, structure, and catalytic activity
of nickel complexes with new chiral binaphthyl-based
NHC-ligands”, J. Organomet.
Chem. 2013, 729, 40-45.
48. Ning Zhao, Liang Chen, Wenshan
Ren, Haibin Song, and Guofu Zi*.
“Synthesis, structure, and catalytic activity of trinuclear
zinc complexes with new chiral biaryl-based NO2
ligands”, J. Organomet.
Chem. 2012, 712, 29-36.
47. Wenshan Ren, Haibin Song, Guofu Zi*,
and Marc D. Walter*. “A bipyridyl thorium metallocene: synthesis, structure and reactivity”, Dalton Trans. 2012, 41, 5965-5973.
46. Zhanbin Zhang, Ning
Zhao, Wenshan Ren, Liang
Chen, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of a new zinc complex derived from a chiral hydroxyazetidine
ligand”, Inorg. Chem. Commun. 2012, 20, 234-237.
45. Wenshan Ren, Guofu Zi,* and Marc D. Walter*. “Synthesis, Structure and Reactivity
of a Thorium Metallocene Containing a 2,
44. Wenshan Ren, Guofu Zi*, De-Cai Fang*, and
Marc D. Walter*.
“A Base-Free Thorium Terminal Imido Metallocene: Synthesis, Structure and Reactivity”, Chem.-Eur.
J. 2011, 17, 12669-12682.
43. Wenshan Ren, Xuebin
Deng, Guofu Zi*,
and De-Cai Fang*. “The Th=C
double bond: an experimental and computational study of thorium poly-carbene complexes”, Dalton
Trans. 2011, 40, 9662-9664.
42. Haibin Song*, Yuqiao
Liu, Dongna Fan, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of rhodium complexes with new chiral binaphthyl-based
NHC-ligands”, J. Organomet.
Chem. 2011, 696, 3714-3720.
41. Wenshan Ren, Ning Zhao, Liang Chen, Haibin
Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity
of an organothorium hydride complex”, Inorg. Chem. Commun.
2011, 14, 1838-1841.
40. Wenshan Ren, Guofu Zi*, De-Cai Fang*, and
Marc D. Walter*.
“Thorium Oxo and Sulfido Metallocenes:
Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem.
Soc. 2011, 133, 13183-13196.
39. Furen Zhang, Haibin Song, and Guofu Zi*.
“Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands”, Dalton Trans. 2011, 40, 1547-1566.
38.
Qiuwen Wang, Furen Zhang, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of organolanthanides with chiral
biphenyl-based tridentate amidate ligands”, J. Organomet. Chem. 2011, 696, 2186-2192.
37.
Haiyan Zhang, Liang Chen, Haibin
Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity
of chiral silver(I) and copper(II) complexes with biaryl-based
nitrogen-containing ligands”, Inorg. Chim. Acta 2011, 366,
320-336.
36.
Furen Zhang, Jiaxin Zhang, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of organoyttrium complexes with chiral binaphthyl-based amidate
ligands”, Inorg. Chem. Commun.
2011, 14, 72-74.
35. Guofu Zi*. “Asymmetric hydroamination/cyclization catalyzed by group 4 metal
complexes with chiral biaryl-based ligands”, J. Organomet. Chem. 2011, 696, 68-75.
(Invited Review Article)
34.
Guofu Zi*,
Furen Zhang and Haibin
Song. “Highly enantioselective hydroaminoalkylation
of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands”, Chem. Commun.
2010, 46, 6296-6298.
33.
Furen Zhang, Haibin Song,
and Guofu Zi*.
“Synthesis, structure, and catalytic activity of titanium complexes with new
chiral 11,12-diamino-9,10-dihydro-9,10-ethanoanthracene-based ligands”, J. Organomet. Chem. 2010, 695, 1993-1999.
32.
Guofu Zi*,
Furen Zhang, Li Xiang, Yue
Chen, Weihai Fang*, and Haibin
Song. “Synthesis and characterization of group 4 metal amides with new C2-symmetric
binaphthyldiamine-based ligands and their use as
catalysts for asymmetric hydroamination/cyclization”,
Dalton Trans. 2010, 39, 4048-4061.
31.
Qiuwen Wang, Haibin Song, Guofu Zi*.
“Synthesis, structure, and catalytic activity of group 4 metal complexes with
new chiral biaryl-based NO2 ligands”, J.
Organomet. Chem. 2010, 695,
1583-1591.
30.
Li Xiang, Furen Zhang, Jiaxin
Zhang, Haibin Song, and Guofu
Zi*. “Synthesis, structure, and catalytic
activity of group 4 complexes with new chiral binaphthyldiamine-based
ligands”, Inorg. Chem. Commun.
2010, 13, 666-670.
29.
Guofu Zi*,
Li Xiang, Xue Liu, Qiuwen
Wang, and Haibin Song. “Synthesis, structure, and
reactivity of yttrium complexes with chiral biaryldiamine-based
N4-ligands”, Inorg. Chem. Commun. 2010, 13, 445-448.
28. Guofu Zi*, Furen Zhang, Xue Liu, Lin Ai, and Haibin Song.
“Synthesis, structure, and catalytic activity of titanium(IV) and zirconium(IV)
amides with chiral biphenyldiamine-based ligands”, J.
Organomet. Chem. 2010, 695,
730-739.
27.
Guofu Zi*.
“Asymmetric hydroamination/cyclization catalyzed by organolanthanide complexes with chiral biaryl-based
ligands”, Dalton Trans. 2009, 9101-9109.
(Invited Perspective Article)
26. Guofu Zi*, Xue Liu, Li Xiang, Haibin
Song. “Synthesis of Group 4 Metal Amides with New Chiral Biaryldiamine-Based Ligands and Their Use as Catalysts for
Asymmetric Hydroamination/Cyclization” Organometallics
2009, 28, 1127-1137.
25.
Haibin Song*, Li-Na Gu, Guofu Zi*.
“Synthesis and X-ray structures of rhodium complexes with new chiral biaryl-based NHC-ligands”, J. Organomet.
Chem. 2009, 694, 1493-1502.
24.
Qiuwen Wang, Li Xiang, Haibin Song, Guofu
Zi*. “Synthesis,
structure, and catalytic activity of binuclear lanthanide complexes with chiral
NOBIN-based NNO ligands”, J. Organomet. Chem. 2009,
694, 691-695.
23.
Zhanbin Zhang, Xuemei Bai, Ruochen Liu, Guofu Zi*.
“Synthesis of new chiral cis-3-aminoazetidines and their use in
catalytic asymmetric reactions”, Inorg. Chim. Acta 2009, 362,
1687-1691.
22.
Xin-Fang Duan,* Jian-Xia
Feng, Guo-Fu
Zi, Zhan-Bin Zhang. “A Convenient Synthesis of Unsymmetrical Pinacols by Coupling of Structurally-Similar Aromatic
Aldehydes Mediated by Low Valent Titanium”, Synthesis 2009, 277-282.
21. Guofu Zi*, Qiuwen Wang, Li Xiang, Haibin Song. “Lanthanide and
group 4 metal complexes with new chiral biaryl-based
NNO-donor ligands”, Dalton Trans. 2008, 5930-5944.
20.
Qiuwen Wang, Li Xiang, Haibin Song, and Guofu
Zi*. “Synthesis
of Amidolanthanides with New Chiral Biaryl-Based NNO Ligands and Their Use as Catalysts for Enantioselective Hydroamination/Cyclization”,
Inorg. Chem. 2008, 47, 4319-4328.
19. Guofu
Zi*, Li Xiang, and Haibin
Song. “Enantioselective Hydroamination/Cyclization
Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)
18.
Li Xiang, Haibin Song, and Guofu
Zi*. “Synthesis, Structure, and Catalytic
Activity of Ti(IV) and Zr(IV) Complexes Derived from
(R)-2,2'-Diamino-1,1'-binaphthyl Based N4-Donor Ligands”, Eur.
J. Inorg. Chem. 2008, 1135-1140.
17. Yadong Zhang, Li Xiang, Qiuwen Wang, Xin-Fang Duan, and Guofu
Zi*.
“Synthesis, structure, and catalytic activity of chiral Cu(II) and Ag(I)
complexes with (S,S
)-1,2-diaminocyclohexane-based N4-donor ligands”, Inorg. Chim. Acta 2008, 361, 1246-1254.
16.
Qiuwen Wang, Li Xiang, and Guofu
Zi*. “Synthesis, structural characterization,
and reactivity of organolanthanides derived from a
new chiral ligand (S)-2-(pyrrol-2-ylmethyleneamino)-2'-hydroxy-1,1'-binaphthyl”,
J. Organomet. Chem. 2008, 693, 68-76.
15. Xin-Fang Duan*, Jing Zeng, Zhan-Bin Zhang, and Guo-Fu
Zi. “A Facile Two-Step Synthesis of 2-Arylbenzofurans Based on the
Selective Cross McMurry Couplings”, J. Org. Chem. 2007, 72, 10283-10286.
14. Li Xiang, Qiuwen Wang, Haibin
Song, and Guofu Zi*. “Synthesis, Structural
Characterization, and Reactivity of Organolanthanides
Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,
13. Zhanbin Zhang, Min Li, and Guofu Zi*. “Synthesis of New Chiral cis-3-Hydroxyazetidines
and Their Application in Diethylzinc Addition to
Aldehydes”, Chirality 2007, 19, 802-808.
12. Noémi Barros, Daniel Maynau, Laurent
Maron, Odile Eisenstein, Guofu Zi, and Richard A. Andersen. “Single but
Stronger UO, Double but Weaker UNMe Bonds: The Tale
Told by Cp2UO and Cp2UNR”, Organometallics 2007,
26, 5059-5065.
11.
Guofu Zi*,
Li Xiang, Yadong Zhang, Qiuwen
Wang, Xiaofang Li, Yuan Yang, and Zhanbin
Zhang. “Synthesis and X-ray structures of new chiral Ag(I) complexes with biaryl-based N4-donor ligands”, J. Organomet. Chem. 2007, 692, 3949-3956.
10. Guofu Zi,
Laura L. Blosch, Li Jia,
and Richard A. Andersen. “Preparation and Reactions of Base-free Bis(1,3,4-tri-t-butylcyclopentadienyl)uranium Methylimide, Cp’2U=NMe,
and Related Compounds”, Organometallics
2005, 24, 4602-4612.
9.
Guofu Zi, Li Jia, Evan L. Werkema, Marc D. Walter, Jochen P.
Gottfriedsen, and Richard A. Andersen. “Preparation and
Reactions of Base-free Bis(1,3,4-tri-t-butylcyclopentadienyl)uranium
Oxide, Cp’2UO”, Organometallics
2005, 24, 4251-4264.
8. Chi Wu, Zuowei Xie, Guangzhao Zhang, Guofu Zi,
Yingfeng Tu, Yali Yang, Ping Cai, and Ting Nie. “Self-assembly assisted polymerization (SAAP):
approaching long multi-block copolymers with an ordered chain sequence and
controllable block length”, Chem. Commun. 2002,
2898-2899.
7. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of ‘Carbons-Adjacent’
nido- and arachno-Carborane
Anions of C2B10 Systems and Their Metal Complexes”, Organometallics 2002, 21, 5415-5427.
6. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Catalytic Property of
Group 4 Metal Carborane Complexes with a iPr2NB-bridged
Constrained-Geometry Ligand”, Organometallics
2002, 21, 3850-3855.
5. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of Lanthanacarboranes Incorporating ‘Carbons-Adjacent’ nido- and arachno-Carborane
Anions of C2B10 System”, Organometallics 2002, 21, 3464-3470.
4. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of Organolanthanide Complexes Derived from A New, Versatile
Boron-Bridged Ligand, iPr2NB(C9H7)(C2B10H11)”,
Organometallics 2002, 21, 1136-1145.
3. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “A Novel Carbons-Adjacent arachno-C2B10
Carborane Tetraanion
Bearing Both Hexagonal and Pentagonal Bonding Face”, Organometallics 2001, 20, 3836-3838.
2. Guofu Zi, Hung-Wing
Li, and Zuowei Xie. “The First Full-sandwich Potassacarborane
and a Novel ‘Carbons-Adjacent’ R
1. Guofu Zi, Qingchuan Yang,
Thomas C. W. Mak, and Zuowei
Xie. “Tetramethylcyclopentadienyl
vs Cyclopentadienyl
Substituents. Synthesis and Structural Characterization of Organolanthanide
Compounds Derived from the Versatile Ligand Me2Si(C5Me4H)(C2B10H11)”,
Organometallics 2001, 20, 2359-2366.
张丛丛同学获“2020年北京师范大学优秀博士学位论文”(2021.2)
张磊同学获“2018年北京师范大学优秀博士学位论文”(2018.12)
方波同学获“2017年北京师范大学优秀博士学位论文”(2017.12)
方波同学获“宝钢教育基金优秀学生奖学金”(2015.11.)
任文山同学获“北京市优秀毕业研究生”称号(2012.7.)
任文山同学获“北京师范大学优秀毕业研究生”称号(2012.7.)
任文山同学获“华藏奖学金”(2011.11.)
任文山同学获“唐敖庆化学奖学金”(2011.11.)
张富仁同学获“北京师范大学优秀毕业研究生”称号(2011.7.)
张富仁同学获“北京师范大学第十届励耘奖学金”二等奖(2010.12.)
刘雪同学获“北京师范大学优秀毕业研究生”称号(2010.7.)
刘雪同学获“北京师范大学研究生综合奖学金”(2009.12)
王秋文同学获“北京师范大学研究生综合奖学金”(2009.12)
向丽同学获“北京师范大学优秀毕业研究生”称号(2009.7.)
向丽同学获“北京师范大学第九届励耘奖学金”一等奖(2008.12.)
王秋文同学获“北京师范大学第九届励耘奖学金”二等奖(2008.12.)
向丽同学获“第六届‘挑战杯’全国大学生创业计划竞赛”银奖(2008.11)
向丽同学获“北京师范大学研究生综合奖学金”(2007.12)
Updated on
October 26, 2023.